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PSM · Environmental health: photochemical smog
Sample itemA city with heavy vehicular traffic and strong sunshine, but little coal burning, has summer haze with eye irritation and high ground-level ozone. Which pollutants react in sunlight to produce this?
Original practice item, not a recalled exam question. Nothing here is recorded.
The answer and the reasoning
C. Nitrogen oxides and hydrocarbons
Photochemical smog forms when sunlight acts on nitrogen oxides and hydrocarbons from vehicle exhaust, producing ozone and peroxyacetyl nitrate that irritate the eyes and respiratory tract. Classical London-type smog, in contrast, results from coal smoke with sulphur dioxide in cold, humid weather.
Option by option
A. Chlorofluorocarbons and halons
Chlorofluorocarbons and halons deplete stratospheric ozone and do not form ground-level smog.
B. Carbon monoxide and carbon dioxide
Carbon monoxide and carbon dioxide are not the reactants that produce ground-level ozone haze.
C. Nitrogen oxides and hydrocarbons (correct)
Correct. Sunlight drives reactions of nitrogen oxides and hydrocarbons to form ozone and other oxidants.
D. Sulphur dioxide and particulate soot
Sulphur dioxide with soot characterises the older coal-smoke smog of cold and humid weather.
Source note: Original NextPrep sample item — pending expert review. This item is original practice material awaiting independent expert review, so confirm important facts in a standard textbook.
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