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PSM · Environmental health
Sample itemIn the chlorination of water, what does the break-point signify?
Original practice item, not a recalled exam question. Nothing here is recorded.
The answer and the reasoning
C. The point beyond which added chlorine appears as free residual chlorine
As chlorine is added, it first reacts with reducing substances and then with ammonia to form chloramines, which peak just before the break-point. Beyond the break-point, the demand is satisfied and further chlorine appears as free residual chlorine.
Option by option
A. The point of maximum formation of chloramines
Combined chloramine concentration peaks before the break-point and then falls.
B. The point at which chlorine demand begins to rise
Chlorine demand is the amount consumed by the water before residual chlorine appears, and it does not begin at the break-point.
C. The point beyond which added chlorine appears as free residual chlorine (correct)
Correct. After the demand is met, added chlorine remains as free residual chlorine.
D. The point at which all bacteria are killed regardless of contact time
Disinfection depends on dose and contact time, so the break-point does not by itself guarantee killing of all bacteria.
Source note: Original NextPrep sample item — pending expert review. This item is original practice material awaiting independent expert review, so confirm important facts in a standard textbook.
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